Hvilke batterityper er der, og hvad er forskellen?
Nickel-Metal Hydride battery (NiMH)
The inscription of NiMH on a battery pack does not automatically guarantee high energy density. A prismatic Nickel-Metal Hydride battery for a mobile phone, for example, is made for slim geometry. Such a pack provides an energy density of about 60Wh/kg and the cycle count is around 300. In comparison, a cylindrical NiMH offers energy densities of 80Wh/kg and higher. Still, the cycle count of this battery is moderate to low. High durability NiMH batteries, which endure 1000 discharges, are commonly packaged in bulky cylindrical cells. The energy density of these cells is a modest 70Wh/kg.
Lithium ION is a family of batteries that also includes Lipo batteries too! Its like saying "Atoms are better than Hydrogen!" Notice how Wikipedia references a LIPO as a Lithium Ion Polymer Battery?
The energy density of lithium-ion is typically twice that of the standard nickel-cadmium
Lithium-ion is a low maintenance battery, an advantage that most other chemistries cannot claim. There is no memory and no scheduled cycling is required to prolong the battery's life. In addition, the self-discharge is less than half compared to nickel-cadmium, making lithium-ion well suited for modern fuel gauge applications. lithium-ion cells cause little harm when disposed.
Despite its overall advantages, lithium-ion has its drawbacks. It is fragile and requires a protection circuit to maintain safe operation. Built into each pack, the protection circuit limits the peak voltage of each cell during charge and prevents the cell voltage from dropping too low on discharge. In addition, the cell temperature is monitored to prevent temperature extremes.
Aging is a concern with most lithium-ion batteries and many manufacturers remain silent about this issue. Some capacity deterioration is noticeable after one year, whether the battery is in use or not. The battery frequently fails after two or three years. It should be noted that other chemistries also have age-related degenerative effects. This is especially true for nickel-metal-hydride if exposed to high ambient temperatures. At the same time, lithium-ion packs are known to have served for five years in some applications.
Manufacturers are constantly improving lithium-ion. New and enhanced chemical combinations are introduced every six months or so. With such rapid progress, it is difficult to assess how well the revised battery will age.
- High energy density - potential for yet higher capacities.
- Does not need prolonged priming when new. One regular charge is all that's needed.
- Relatively low self-discharge - self-discharge is less than half that of nickel-based batteries.
- Low Maintenance - no periodic discharge is needed; there is no memory.
- Specialty cells can provide very high current to applications such as power tools.
- Requires protection circuit to maintain voltage and current within safe limits.
- Subject to aging, even if not in use - storage in a cool place at 40% charge reduces the aging effect.
- Transportation restrictions - shipment of larger quantities may be subject to regulatory control. This restriction does not apply to personal carry-on batteries.
- Expensive to manufacture - about 40 percent higher in cost than nickel-cadmium.
- Not fully mature - metals and chemicals are changing on a continuing basis.
This article is very, very poor. Lithium-Polymer batteries have 20% or higher energy density than Lithium-Ions. That is why a smaller Li-Poly battery can have the same capacity as a Li-Ion. It is also one of the reasons they are more expensive. If you read the source material for this article, you can see that "energy density" was mentioned as an advantage over Ni-Cad batteries, not Li-Poly.
The lithium polymer battery
The lithium-polymer differentiates itself from conventional battery systems in the type of electrolyte used. The original design, dating back to the 1970s, uses a dry solid polymer electrolyte. This electrolyte resembles a plastic-like film that does not conduct electricity but allows ions exchange (electrically charged atoms or groups of atoms). The polymer electrolyte replaces the traditional porous separator, which is soaked with electrolyte.
The dry polymer design offers simplifications with respect to fabrication, ruggedness, safety and thin-profile geometry. With a cell thickness measuring as little as one millimeter (0.039 inches), equipment designers are left to their own imagination in terms of form, shape and size.
Unfortunately, the dry lithium-polymer suffers from poor conductivity. The internal resistance is too high and cannot deliver the current bursts needed to power modern communication devices and spin up the hard drives of mobile computing equipment. Heating the cell to 60°C (140°F) and higher increases the conductivity, a requirement that is unsuitable for portable applications.
To compromise, some gelled electrolyte has been added. The commercial cells use a separator/ electrolyte membrane prepared from the same traditional porous polyethylene or polypropylene separator filled with a polymer, which gels upon filling with the liquid electrolyte. Thus the commercial lithium-ion polymer cells are very similar in chemistry and materials to their liquid electrolyte counter parts.
Lithium-ion-polymer has not caught on as quickly as some analysts had expected. Its superiority to other systems and low manufacturing costs has not been realized. No improvements in capacity gains are achieved - in fact, the capacity is slightly less than that of the standard lithium-ion battery. Lithium-ion-polymer finds its market niche in wafer-thin geometries, such as batteries for credit cards and other such applications.
- Very low profile - batteries resembling the profile of a credit card are feasible.
- Flexible form factor - manufacturers are not bound by standard cell formats. With high volume, any reasonable size can be produced economically.
- Lightweight - gelled electrolytes enable simplified packaging by eliminating the metal shell.
- Improved safety - more resistant to overcharge; less chance for electrolyte leakage.
- Lower energy density and decreased cycle count compared to lithium-ion.
- Expensive to manufacture.
- No standard sizes. Most cells are produced for high volume consumer markets.
- Higher cost-to-energy ratio than lithium-ion
Is One Better than the Other?
Both lithium-ion and lithium-polymer batteries have their pros and cons. Typically, the advantages of a lithium-ion is their high power density, lack of what’s called the memory effect (when batteries become harder to charge over time), and their significantly lower cost than lithium-polymer. In the words of Wired, “Lithium-ion batteries are incredibly efficient. They stuff freakish amounts of energy in a tiny package.” But, as anyone might have seen with the recent saga of a certain cellphone brand being banned from flights, lithium-ion batteries are inherently unstable, suffer from aging, and are potentially dangerous. If the barrier that separates the positive and negative electrode is ever breached, the chemical reaction can cause combustion (fire). As Li-ion batteries have become more popular in consumer electronics, businesses have tried to lower costs by cutting corners. While quality batteries are perfectly safe, you should always be careful when buying no-name brands.
Lithium-polymer batteries, on the other hand, are generally robust and flexible, especially when it comes to the size and shape of their build. They are also lightweight, have an extremely low profile, and have a lower chance of suffering from leaking electrolyte. But lithium-polymer batteries aren’t perfect either: they are significantly more costly to manufacture, and they do not they have the same energy density (amount of power that can be stored) nor lifespan as a lithium-ion.